(±)-1,1'-Bi(2-naphthylamine), 97%, Thermo Scientific Chemicals

Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1?-binaphthalenyl-2,2?-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The enantioselective direct aldol reaction, organocatalyzed by recoverable BINAM- prolinamide derivatives can be highly accelerated by a catalytic amount of a carboxylic acid without a detrimental of the obtained enantioselectivities.

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Applications
Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1′-binaphthalenyl-2,2′-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The enantioselective direct aldol reaction, organocatalyzed by recoverable BINAM- prolinamide derivatives can be highly accelerated by a catalytic amount of a carboxylic acid without a detrimental of the obtained enantioselectivities.

Solubility
Insoluble in water

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.