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(Trifluoromethyl)trimethylsilane, 95%, Thermo Scientific Chemicals

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Quantity:
1 g
25 g
5 g
81290-20-2
C5H11F3Si
156.22
MFCD00145454
MTYSDPUZDZURPP-UHFFFAOYSA-N
trifluoromethyl trimethylsilane,trimethyl trifluoromethyl silane,trifluoromethyltrimethylsilane,ruppert's reagent,tms-cf3,tfmtms,silane, trimethyl trifluoromethyl,unii-a009786qpj,trimethylsilyl trifluoromethane,ruppert-prakash reagent
552549
trimethyl(trifluoromethyl)silane
CC(C)(C)[SiH2]C(F)(F)F

Product code B20347 Thermo Scientific

Catalog number ALF-B20347-03

  • INR 2,673.00 / EA
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Description

It is employed as a valuable reagent for trifluoromethylation of electrophilic substrates. It is also use an the nucleophilic addition of the trifluoromethyl group to aldehydes and ketones. It generates trifluoromethide with catalytic amounts of F- (TBAF or CsF) and reacts with carbonyl compounds to produce trifluoromethylated alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is employed as a valuable reagent for trifluoromethylation of electrophilic substrates. It is also use an the nucleophilic addition of the trifluoromethyl group to aldehydes and ketones. It generates trifluoromethide with catalytic amounts of F- (TBAF or CsF) and reacts with carbonyl compounds to produce trifluoromethylated alcohols.

Solubility
Soluble in alcohol, THF, ether, dichloromethane, aromatic and aliphatic hydrocarbons. Soluble in water(with white smokes).

Notes
Moisture sensitive. Store away from oxidizing agents and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Specifications

Boiling Point 54°C to 55°C
Quantity 1 g
Linear Formula (CH3)3SiCF3
UN Number UN1993
Beilstein 4241868
Flash Point −10°C (14°F)
Solubility Information Soluble in alcohol,THF,ether,dichloromethane,aromatic and aliphatic hydrocarbons. Soluble in water(with white smokes).
Formula Weight 142.2
Percent Purity 98%
Refractive Index 1.3305
Sensitivity Moisture sensitive
Density 0.962
Chemical Name or Material (Trifluoromethyl)trimethylsilane
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Safety and Handling

GHS H Statement
H225-H315-H319-H335
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c

H225-H315-H319-H335

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.

EINECSNumber : 000-000-0

TSCA : No

Recommended Storage : Ambient temperatures